Where is PST File Located?
Default Location of PST File
By default, Outlook PST file is located at: C:\Documents and Settings\%username%\Local Settings\Application Data\Microsoft\Outlook\.
Default Location for Windows Vista Users
By default, Windows Vista, Outlook PST file is located at: C:\Users\%username%\AppData\Local\Microsoft\Outlook\.
It is better not to connect to a PST file located on a network share as it is not a recommendable thing because problems like data loss, damage or corruption may likely to occur.

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